Large-area thin-film synthesis of photoactive Cu 3 PS 4 thiophosphate semiconductor with 0–14 pH stability range

W4415148740 · 수집 2026-10-04 18:16:49

T10321 Quantum Dots Synthesis And Properties

CoT 라벨링

라벨링 전

PDF 파일

저장된 PDF 없음

기본 정보

DOI 제목 발행년도 저널 URL 페이지 열기 PDF URL PDF 열기 발행기관 피인용수 라이선스

추가 정보 초록

Metal phosphosulfide materials have sparked growing interest due to their wide range of properties and applications. Despite a sizable presence in the bulk materials synthesis literature, reports of phosphosulfide thin films are extremely scarce. This may be due to the hazardous, volatile, and corrosive nature of many phosphorus and sulfur precursors, combined with the high sulfur chemical potential needed to incorporate large amounts of this volatile element in the (PS4)3- and (P2S6)4- thiophosphate anions that are common in this material family. To overcome these limitations, we introduce directional-and-diffuse multi-anion reactive sputtering (DADMARS). DADMARS uniquely combines sputtered metal sources, reactive gas, and a thermally cracked evaporated nonmetal source with a high chemical potential to gain access to challenging multi-anion chemistries in thin-film form. In this study, we employ Cu, PH3, and S x as the sputtered, gaseous, and evaporated sources to deposit polycrystalline Cu3PS4 thin-film thiophosphate semiconductors with the narrowest X-ray diffraction peaks recorded for a phosphosulfide thin film. Single-phase Cu3PS4 can be grown over relatively large areas (8 × 8 cm2 and extendable) at temperatures down to 375 °C, which is lower than for similar sulfide semiconductors CuInS2 and Cu2ZnSnS4. This suggests potential compatibility with established device fabrication processes. Cu3PS4 thin films exhibit remarkable environmental, radiation, and chemical stability, with negligible etch rates in the 0-14 pH range. Thin-film Cu3PS4 is a p-type semiconductor with a bandgap of 2.3-2.5 eV, strong light absorption, and detectable photoluminescence at room temperature. This combination of stability and optoelectronic properties positions Cu3PS4 as a promising earth-abundant semiconductor for photoelectrochemical applications.

본문 활용가능성

이력 0건

아직 편집 이력이 없습니다. 저장할 때마다 이전 내용이 여기에 백업됩니다.

Large-area thin-film synthesis of photoactive Cu <sub>3</sub> PS <sub>4</sub> thiophosphate semiconductor with 0–14 pH stability range

CoT 라벨링

PDF 파일

이력 0건