[HgX 2 ] Linear Group Enabled Ultraviolet Birefringent Crystal RbHg 5 Br 11 with Strong Optical Anisotropy and Wide Bandgap

W4414081633 · 수집 2026-10-04 18:16:39

T11878 Solid-state spectroscopy and crystallography

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Birefringent crystals are pivotal for modern optical modulation technologies, yet developing high-performance birefringent materials with large birefringence (Δn), wide bandgaps, and scalable synthesis remains a significant challenge. Different from the traditional planar [MQ3] and distorted [MQn] (n ≥ 4) polyhedral units, a "linear-group" design strategy is proposed, targeting heavy-metal halides with [HgX2] (X = halides) coordination modes to exploit their inherent polarizability anisotropy. Through systematic experimental investigations in the ternary A-Hg-X (A = Rb, Cs; X = Br, I) system, six novel Hg-based halides were synthesized. Notably, RbHg5Br11 with linear [HgBr2] units demonstrates excellent optical properties, including a wide bandgap (3.73 eV) and large Δn( cal. ) (0.35@546 nm). Importantly, the compound displays a good crystal growth habit, and the high-quality RbHg5Br11 single crystal can be grown by the simple solution method. Theoretical calculations reveal that the strong optical anisotropy arises from the aligned [HgBr2] linear units. The results demonstrate that RbHg5Br11 is a promising birefringent material and give some new insights for designing high-performance optical materials based on the linear units with high polarizability anisotropy.

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[HgX <sub>2</sub> ] Linear Group Enabled Ultraviolet Birefringent Crystal RbHg <sub>5</sub> Br <sub>11</sub> with Strong Optical Anisotropy and Wide Bandgap

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