Rechargeable PEM Fuel-Cell Batteries Using Quinones as Hydrogen Carriers

W1988348346 · 수집 2026-10-04 18:12:18

T10409 Fuel Cells and Related Materials

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Rechargeable fuel-cell batteries (RFCBs) that employ organic chemical hydrides as hydrogen storage media have potential as next-generation power sources; however, the reversible storage and release of hydrogen remains a significant challenge. In particular, the hydrogenation of organic compounds during cell charge is difficult to achieve with 100% conversion. However, this report demonstrates that quinones, especially anthraquinone (AQ), can function as a hydrogen carrier for RFCBs, where AQ is hydrogenated to anthrahydroquinone (AH2Q) during charge and AH2Q is dehydrogenated to AQ during discharge. This redox reaction occurred at a more positive potential than that for hydrogen reduction, so that undesired hydrogen production can be avoided by adjusting the charge voltage to 1 V. The resulting RFCB maintained 100% electrical capacity at room temperature, 91% at 50°C, and 63% at 75°C of the respective initial performance with coulombic efficiencies greater than 90% after 300 cycles. Moreover, the RFCB functioned as a secondary battery with energy densities of 0.8–3.4 Wh kg−1, power densities of 9.5–258.9 W kg−1, and as a fuel cell with power densities of 0.001–0.26 W cm−3. Based on the performance and degradation data, the limitations of this RFCB and directions for future research are discussed.

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